Advanced Functional Layer-by-Layer Nanocoatings: Graphene, MOFs, MXenes and More

Vann Ness Award Lecture
Jodie Lutkenhasu
Professor, Artie McFerrin Department of Chemical Engineering
Texas A&M University
Ricketts 211, Rensselaer Polytechnic Institute
Wed, October 05, 2016 at 9:15 AM
Refreshments will be served one half hour prior to each lecture.

Coatings and thin films are found in everyday objects as a means to introduce functionality or enhance the performance of the underlying substrate. We examine layer-by-layer assembly as a versatile means to produce conformal coatings with functionalities ranging from thermo-responsiveness to energy storage and electronic conductivity. In this technique, complementary species are adsorbed from aqueous solutions to a substrate, producing a robust coating facilitated by non-covalent interactions. Our group has exhibited graphene-based nanocoatings as battery and capacitor electrodes that can be deposited in a spray-on approach. These have promise in the area of structural energy and power, where the integration of batteries and capacitors into every day objects is of interest. Most recently, we have demonstrated nanocoatings containing alternating layers of metal organic frameworks (MOFs) and polyelectrolyte. MOFs have long been of interest for their high surface area and porosity and for applications ranging from gas storage to separations. These coatings can be deposited by simple immersion-based LbL assembly or even spray-on LbL assembly, rendering them suitable for deposition over large areas. Similarly, we have demonstrated the deposition of MXenes by LbL assembly. MXenes are 2-dimensional sheets derived from MAX-phases and have high conductivity and robust mechanical properties. MXenes are emerging as an interesting alternative to graphene sheets, yet they are notoriously difficult to process. Our processing approach yields flexible, stretchable conductive MXene-based coatings on a variety of substrates. We also examine the fundamental properties of layer-by-layer assemblies, particularly those containing only polyelectrolytes. These polyelectrolyte-based assemblies exhibit a glass-transition-like event in the presence of water, rendering them thermo-responsive. We investigate the origin of this transition and the role of water as a plasticizer. Broadly speaking, layer-by-layer assemblies have tremendous potential in deploying functionality into coatings in a mix and match materials-based approach.

The Van Ness Award is made in recognition of the achievements of the late H.C. Van Ness, Institute Professor Emeritus at Rensselaer Polytechnic Institute. It is presented annually to honor a chemical engineer who has made seminal contributions to the profession. The Van Ness Award Lecture Series is sponsored by a generous endowment from Edward ’62 and Nancy Feltham.

Jodie Lutkenhasu

Jodie L. Lutkenhaus is the William and Ruth Neely Faculty Fellow and an Associate Professor in the Artie McFerrin Department of Chemical Engineering at Texas A&M University. Lutkenhaus received her B.S. in Chemical Engineering in 2002 from The University of Texas at Austin and her Ph.D in Chemical Engineering in 2007 from Massachusetts Institute of Technology. Following a postdoctoral position at University of Massachusetts Amherst, she joined the faculty at Yale in 2008. In 2010, she moved to Texas A&M University and was promoted to Associate Professor in 2015. 

Current research areas include polyelectrolytes, electroactive polymers, energy storage, and anti-corrosion coatings. She has received recognitions including the NSF CAREER, AFSOR YIP, 3M Non-tenured Faculty Award, ACS PRF Doctoral New Investigator, Kaneka Junior Faculty Award, and an ACS PMSE Young Investigator.  Other awards include: World Technology Finalist (Energy) 2015; George Armistead, Jr. ’23 Faculty Excellence Teaching Award 2015 and 2014; TEES Select Young Faculty 2015 and 2013; and Montague-CTE Scholar 2014.

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